When i had my Fiat Coupe 20vt, I ran that on Shell V max, or more then often, Tesco 99. At a RR day, the Tesco 99, gave me several more bhp, over 97 ron petrol. Reason i know this, It was the week before the RR, and there was no Tesco 99, so i filled up with 95 ron. Within a mile or so, the car had a little hiccup, and the response from the car, was worse. As soon as i refilled with Tesco 99, again, the car hiccuped [map reset?], and response was back!
As for the newer Shell V Power, I dont think Shell quote an actual ron rating? But, i know it has a very high detergent content.
Andy.